Partial oxidation of methanol to formaldehyde in an annular reactor
نویسندگان
چکیده
منابع مشابه
Simulation of Methane Partial Oxidation in Porous Media Reactor for Hydrogen Production
The enactment of strict laws on reducing pollution and controlling combustion has given rise to the necessity of considering a new approach to energy supply in the future. One such approach is the use of hydrogen as an alternative to fossil fuels. Hydrogen and synthesis gas are typically produced through the partial oxidation of methane in porous media. This process was theoretically simula...
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The oxidation of methanol to formaldehyde on silica supported vanadium oxide is studied by density functional theory. For isolated vanadium oxide species silsesquioxane-type models are adopted. The first step is dissociative adsorption of methanol yielding CH3O(O=)V(O-)2 surface complexes. This makes the O=V(OCH3)3 molecule a suited model system. The rate-limiting oxidation step involves hydrog...
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is not favorable (AH = + 3 1.5 kcal). Our conclusion is that an important catalytic site involves two adjacent surface dioxo units (the dual dioxo site), with each dioxo site extracting one H in a sequence of steps. The required dual dioxo site exists on the (010) surface of MOO, but does not exist on the other low index surfaces. This mechanism is supported by atmospheric pressure experimental...
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Atmospheric methanol measurement using selective catalytic methanol to formaldehyde conversion S. J. Solomon, T. Custer, G. Schade, A. P. Soares Dias, and J. Burrows Institute of Environmental Physics, University of Bremen, Bremen, Germany GRECAT-Grupo de Estudos de Catalise Heterogenea, Universidade Tecnica de Lisboa, Lisbon, Portugal presently with: Department of Atmospheric Sciences, Texas A...
متن کاملDensity functional theory study of the oxidation of methanol to formaldehyde on a hydrated vanadia cluster
Density functional theory was used to study the mechanism for the oxidation of methanol to formaldehyde. A vanadium oxide cluster O=V(OH)(3) has been utilized to represent the catalytic system under hydrated conditions, i.e., in the presence of V-OH hydroxyl groups. Two types of methoxy-intermediates have been considered: a penta-coordinate methoxy-intermediate (OH)(4)V(OCH(3)) and a tetrahedra...
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ژورنال
عنوان ژورنال: Chemical Engineering Journal
سال: 2021
ISSN: 1385-8947
DOI: 10.1016/j.cej.2021.130141